Application and description of yin and yang resin

Ion exchange technology has a long history, and certain natural materials such as zeolites and sulfonated coals obtained by sulfonation with coal can be used as ion exchangers.
Macroporous strong acid cation exchange resin: 001x7, 201x7/205x7, 201x7, 001x4, 001x14, 005x7, D72, D61, D001-CC, D81, NKC-9 dry hydrogen resin; various gel type, macroporous weak acid cation Resin: D113, D152, D151, 110; various gel-type, macroporous strong base anion exchange resins: 201x4, 201x7, D3520, D290, D296, D261, 280, D284; various macroporous weak base anions Exchange resin: D301T, D301R, D315, D370, D371, D392, D380, D382; Chelating ion exchange resin: D401, D403, D418; various macroporous pharmaceutical adsorption resins: D3520, D4006, D4020, H103, H107, H1020, X-5, AB-8, NKA, LX-ion exchange resins are polymers with corresponding functional groups. Other supplements:
(1) Strongly acidic cationic resin Such a resin contains a large amount of a strong acidic group such as a sulfonic acid group -SO3H, and is easily dissociated from H+ in a solution, so that it is strongly acidic. After the resin is dissociated, the negatively charged groups contained in the bulk, such as SO3-, can adsorb other cations in the bound solution. These two reactions exchange H+ in the resin with the cations in the solution. Strongly acidic resins have strong dissociation ability and can dissociate and produce ion exchange in acidic or alkaline solutions.
After the resin has been used for a period of time, it is subjected to a regeneration treatment in which the ion exchange reaction is carried out in the opposite direction with a chemical to return the functional group of the resin to its original state for reuse. The cationic resin as described above is subjected to regeneration treatment with a strong acid, at which time the resin releases the adsorbed cation and combines with H+ to restore the original composition.
(2) Weakly acidic cationic resin Such a resin contains a weakly acidic group such as a carboxyl group-COOH, which is capable of dissociating H+ in water and being acidic. The remaining negatively charged groups after the dissociation of the resin, such as R-COO- (R is a hydrocarbon group), can adsorb to other cations in the solution to cause cation exchange. The acidity of this resin is weak, it is difficult to dissociate and ion exchange at low pH, and it can only work in alkaline, neutral or slightly acidic solutions (such as pH 5-14). Such resins are also regenerated with acid (more readily regenerated than strongly acidic resins).
(3) Strongly basic anion resin. Such a resin contains a strong basic group such as a quaternary amine group (also known as a quaternary amine group)-NR3OH (R is a hydrocarbon group), which can dissociate OH- in water. Strongly alkaline. The positively charged group of this resin binds to the anion in the solution to cause anion exchange.
This resin is highly dissociable and works well at different pHs. It is regenerated with a strong base such as NaOH.
(4) Weakly basic anion resins These resins contain weakly basic groups such as primary amino groups (also known as primary amine groups) - NH2, secondary amino groups (secondary amine groups) - NHR, or tertiary amine groups ( Tertiary amine groups -NR2, which are weakly alkaline in the water to dissociate OH-. The positively charged group of this resin binds to the anion in the solution to cause anion exchange. This resin in most cases adsorbs all other acid molecules in the solution. It can only work under neutral or acidic conditions (eg pH 1 to 9). It can be regenerated with Na2CO3, NH4OH.

In addition to the above two series of styrene and acrylic, the ion exchange resin can also be made by polymerizing other organic monomers. Examples include phenolic (FP), epoxy (EPA), vinylpyridine (VP), and urea formaldehyde (UA).

Introduction to the variety of ion exchange resins:
Ion exchange resins are available in many manufacturers and many varieties at home and abroad. There are dozens of domestic manufacturing plants, mainly Shanghai Resin Factory, Tianjin Bohong Resin Technology Co., Ltd., Chenguang Chemical Research Institute Resin Factory, Tianjin Nanda Resin Technology Co., Ltd., etc.; more famous foreign companies such as Rohm & Hass Amberlite series, Dow Chemical's Dowex series, French Duolite series and Asmit series, Japan's Diaion series, as well as Ionac series, Allassion series and so on. Most of the resin grades are specified by each manufacturer or country. Some foreign products use the letter C for cationic resin (C is the first letter of cation), A for anionic resin (A is the first letter of Anion), such as Amberlite's IRC and IRA are cation resin and anion resin, respectively. Represents cation resin and anion resin, respectively. China's Ministry of Chemical Industry regulations (HG2-884-76), the type of ion exchange resin consists of three Arabic numerals. The first digit represents the classification of the product: 0 for strong acidity, 1 for weak acidity, 2 for strong alkalinity, 3 for weakly basic, 4 for chelation, 5 for amphoteric, and 6 for redox. The second digit represents a different skeleton structure: 0 represents a styrene system, 1 represents an acrylic system, 2 represents a phenolic system, and 3 represents an epoxy system. The third digit is the sequence number, which is used to distinguish the difference between the matrix, the crosslinking group, and the like. In addition, the macroporous resin is preceded by a letter D. Therefore, D001 is a macroporous strong acid styrene resin.

Brand Resin structure product name Functional basis Full exchange
(a) mmol/g (dry)
(b)mmol/ml (wet)
Watery
(%)
Foreign reference product use
1 D301R Styrene-DVB Macroporous weakly basic styrene anion exchange resin –N(CH 3 ) 2 (a) ≥ 4.8
(b) ≥ 1.4
50-65 (US) Amberlite IRC-84 Mutang desalination, water treatment, electroplating of chromium-containing wastewater treatment, good pollution resistance.
2 D301G Styrene-DVB Macroporous weakly basic styrene anion exchange resin –N(CH 3 ) 2 (a) ≥ 4.2
(b) ≥ 1.1
60~72 (H) (US) Amberlite IRC-84 Hydrometallurgy extracts gold from pulp.
3 D301T Styrene-DVB Macroporous weakly basic styrene anion exchange resin –N(CH 3 ) 2 (a) ≥ 9.5 (H type)
(b) ≥ 3 (H type)
50~60 (H) (US) Amberlite IRA-93 (Germany) Wofatit AD-41 Starch sugar desalting and decolorization, water treatment
4 D392 Styrene-DVB Macroporous weakly basic styrene anion exchange resin –NH 2 (a) ≥ 10.8 (type H)
(b) ≥ 4.2 (H type)
45~52 In the pharmaceutical industry, antibiotics are refined and decolored.
5 D380 Styrene-DVB Macroporous weakly basic styrene anion exchange resin –NH 2 (a) ≥ 7.0
(b) ≥ 2.4
42~48 Streptomycin extraction and the like.
6 D382 Styrene-DVB Macroporous weakly basic styrene anion exchange resin –NHCH 3

The properties and parameters of various resins can be found in the ion exchange resin manual and products.

Brand
product name
Full exchange
Foreign reference product
use
001×1
Strong acid styrene cation exchange resin
(a) ≥ 4.5
(b) ≥ 0.4
(US) Amberlite IR-116
(US) Dowex 50×1
Antibiotic refining, pharmaceutical and chemical industries.
001×2
Strong acid styrene cation exchange resin
(a) ≥ 4.5
(b) ≥ 0.6
(US) Dowex 5×2
Antibiotic refining, pharmaceutical and chemical industries.
001×3
Strong acid styrene cation exchange resin
(a) ≥ 4.5
(b) ≥ 1.0
(Day) Diaion SK-103
Antibiotic refining, pharmaceutical and chemical industries.
001×4
Strong acid styrene cation exchange resin
(a) ≥ 4.5
(b) ≥ 1.3
(US) Amberlite IR-118
Preparation of high purity water and refining of antibiotics.
001×7
Strong acid styrene cation exchange resin
(a) ≥ 4.5
(b) ≥ 1.8
(US) Amberlite IR-120
(US) Dowex 50
(Russia) KY-2
(Day) Diaion SK-IA
Hard water softening, pure water preparation, hydrometallurgy, rare element separation.
002×7
Strong acid styrene cation exchange resin
(a) ≥ 4.4
(b) ≥ 1.8
-
Large particle size for high flow rate water treatment.
003×7
Strong acid styrene cation exchange resin
(a) ≥ 4.5
(b) ≥ 1.8
-
Uniform particle size, suitable for amino acid and separation of rare elements.
004×7
Strong acid styrene cation exchange resin
(a) ≥ 4.3
(b) ≥ 1.6
-
Hard water softening, pure water preparation, etc.
001×8
Strong acid styrene cation exchange resin
(a) ≥ 4.5
(b) ≥ 2.0
(US) Amberlite IR-120
(US) Dowex 50
(Russia) KY2-8
(Day) Diaion SK-IB
Hard water softening, pure water preparation, hydrometallurgy, rare element separation.
001×7
×7
Strong acid styrene cation exchange resin
(a) ≥ 4.5
(b) ≥ 2.0
-
Water treatment.
001×
14.5
Strong acid styrene cation exchange resin
(a) ≥ 3.8
(b) ≥ 2.0
(US) Amberlite ER-124
Pharmaceutical industry, antibiotics refining.
D072
Macroporous strong acid styrene cation exchange resin
(a) ≥ 4.2
(b) ≥ 1.4
(US) Amberlyst-15
(Day) Diaion HPK-16
Organic reaction catalysis, high-speed mixed bed water treatment, etc.
D061
Macroporous strong acid styrene cation exchange resin
(a) ≥ 4.2
(b) ≥ 1.4
-
Food industry, amino acid refining, organic reaction catalysis, water treatment, etc.
D001-
CC
Macroporous strong acid styrene cation exchange resin
(a) ≥ 4.1
(b) ≥ 1.6
-
Organic reaction catalysis, bio-refining of amino acid refining, etc.
NKC-9
Macroporous strong acid styrene cation exchange resin
(a) ≥ 4.7
(b) ≥ 1.5
(US) Amberlyst 15
Organic reaction catalysis.
D001SS
Macroporous strong acid styrene cation exchange resin
(a) ≥ 4.2
(b) ≥ 2.0
-
The special sugar juice for the sugar industry is decalcified and the expansion rate is small.
+ Total exchange: (a) mmol/g (dry) (b) mmol/ml (wet)
* Resin structure: Styrene-DVB

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